L. F. Koroleva, R. A. Savrai, E. Yu. Prosviryakov, V. A. Kostarev, S. V. Pavlyshko, P. V. Kostarev
THE EFFECT OF ABRASIVE ADDITIVES ON THE TRIBOTECHNICAL PROPERTIES OF LUBRICANTS FOR THE WHEEL–RAIL SYSTEM
DOI: 10.17804/2410-9908.2023.1.054-064 The paper studies the polishing power of a tribochemically active abrasive material based on a solid solution of iron and aluminum oxides, as well as a solid solution of aluminum and iron oxides modified by zirconium oxide and yttrium oxide additives, and the tribotechnical properties of a lubricant doped with these abrasive materials. The modified Al2O3·Fe2O3·ZrO2·Y2O3 powders prove to have an essentially higher polishing power producing a considerably lower surface roughness than that of the unmodified Al2O3·Fe2O3 powder. By varying the content of the modifying oxides, one can change the tribochemical activity of the abrasive powder and select the best composition depending on the material to be polished. The addition of these abrasive powders is shown to have an essential effect on the tribotechnical properties of the lubricant for the wheel–rail contact. The laboratory testing of the lubricant compositions suggests their effective applicability to the wheel–rail contact.
Acknowledgement: This study was performed within the state assignments for the IES UB RAS, reg. nos. AAAA-A18-118020790142-9 and AAAA-A18-118020790147-4.
Optical profilometry and tribotechnical tests were performed in Collective Use Center “Plas-tometriya” of the Institute of Engineering Science UB RAS. Keywords: tribochemically active abrasive material, polishing ability, surface roughness, lubrication for the wheel–rail system, welding load, wear spot diameter References:
- Tuvshintur B., Vinokurov D.I., Yakimova G.A., Gozbenko V.E. Lubricants for the wheel-rail system. Solution of an excessive wear problem with production wastes used. Systems. Methods. Technologies, 2015, No. 3 (27), pp. 23–31. (In Russian).
- Artemov A.S. Polishing nanodiamonds. Physics of the Solid State, 2004, vol. 46, pp. 687–695. DOI: 10.1134/1.1711453.
- Jackson M.J., Mills B., Hitchiner M.P. Controlled wear of vitrified abrasive materials for precision grinding applications. Sadhana, 2003, vol. 28, No. 5, pp. 897–914. DOI: 10.1007/BF02703320.
- Bakharev V.P. Dispersion of Ceramics and Composites in Diamond Finishing by Free Abrasive. Russ. Engin. Res., 2009, vol. 29, No. 2, pp. 162–168. DOI: 10.3103/S1068798X09020129.
- Filatov Y.D., Yashchuk V.P., Filatov A.Y., Heisel U., Storchak M. and Monteil G. Assessment of surface roughness and reflectance of nonmetallic products upon diamond abrasive finishing. J. Superhard Mater., 2009, vol. 31, pp. 338–346 DOI: 10.3103/S1063457609050098.
- Storozhenko P.A., Guseinov Sh.L., and Malashin S.I. Nanodispersed powders: synthesis methods and practical applications. Nanotekhnol. Russia, 2009, vol. 4, Nos. 5–6, pp. 262–274. DOI: 10.1134/S1995078009050024.
- Pokropivnyi V.V., Silenko P.M. Silicon carbide nanotubes and nanotubular fibers: synthesis, stability, structure and classification. Theor. Exp. Chem., 2006, vol. 42, No. 1, pp. 3–15. DOI: 10.1007/s11237-006-0010-y.
- Khanra A.K. Production of boron carbide powder by carbothermal synthesis of gel material. Bull. Mater. Sci., 2007, vol. 30, No. 2, pp. 93–96. DOI: 10.1007/s12034-007-0016-7.
- Bogdanov S.P. Influence of superstoichiometric boron on the synthesis of cubic boron nitride. Glass Physics and Chemistry, 2008, vol. 34, No. 3, pp. 336–339. DOI: 10.1134/S1087659608030164.
- Degtyareva E.V., Kabakova I.I., Skorodumova E.B., Armyanovskii V.E. An abrasive-resistant corundum ceramic for drawing microwires. Refractories, 1982, vol. 23, Nos. 1–2, pp. 82–87. DOI: 10.1007/BF01397952.
- Garshin A.P., Gropyanov V.M., and Lagunov Yu.V. Abrazivnye materialy [Abrasive Materials]. Leningrad, Mashinostroenie Publ., 1983. (In Russian).
- Viktorov V.V., Fotiev A.A., and Badich V.D. Abrasive and Thermal Properties of Al2O3–Cr2O3 Solid Solutions. Inorg. Mater., vol. 32, No. 1, pp. 55–57.
- Kotov Yu.A., Samatov O.M. Characteristics of aluminum oxide powders produced by impulse wire heating. Poverkhnost, 1994, nos. 10–14, pp. 90–94. (In Russian).
- Belousov V.M., Chertov V.M., Rozhkova É.V., Litvin V.I. and Zazhigalov V.A. A sol-gel method for synthesizing porous iron-aluminum oxide substances and regulating their physicochemical characteristics. Theor. Exp. Chem., 1997, vol. 33, No. 2, pp. 103–105. DOI: 10.1007/BF02765955.
- Koroleva L.F. Tribochemical Activity of Mixed-Oxide Abrasive Materials in Metal Polishing. Fiz. Khim. Obrab. Mater., 2006, No. 4, pp. 84–92. (In Russian).
- Kim Nan-Hoon, Lim Jond-Heun, Kim Sang-Yong, Chang Eui-Goo. Semi-abrasive free slurry with acid colloidal silica for copper chemical mechanical planarization. Journal of Material Science: Materials in Electronics, 2005, vol. 16, pp. 629–632. DOI: 10.1007/s10854-005-3241-0.
- Marchenko E. A. O prirode razrusheniya poverkhnosti metallov pri trenii [On the Nature of Metal Surface Fracture in Friction]. Moscow, Nauka Publ., 1979. (In Russian).
- Rebinder P.A. The Significance of physicochemical processes in mechanical failure and processing of solids in engineering. Vestnik AN SSSR, 1940, No. 8, pp. 5–28. (In Russian).
- Koroleva L.F. Modified nanoparticle oxides for final polishing. Diagnostics, Resource and Mechanics of materials and structures, 2016, iss. 2, pp. 48–73. DOI: 10.17804/2410-9908.2016.2.048-073. Available at: http://dream-journal.org/DREAM_Issue_2_2016_Koroleva_L.F._048_073.pdf
- Koroleva L.F. Synthesis and abrasive properties of nanoparticulate modified solid solutions of aluminum and iron oxides. Inorganic Materials, 2019, vol. 55 (6), pp. 556–562. DOI: 10.1134/S0020168519060074.
- Koroleva L.F. Synthesis and abrasive properties of nanoparticulate MoO2-modified Al2-хFeхO3 and Fe2-yAlyO3 solid solutions. Inorg. Materials, 2010, vol. 46, No. 12, pp. 1330–1336. DOI: 10.1134/S0020168510120113.
- Koroleva L.F. Final polishing of metals to obtain nanoroughened surface. Nanotechnologies in Russia, 2012, vol. 7, Nos. 1–2, pp. 67–75. DOI: 10.1134/S1995078012010119.
- Koroleva L.F. Nanoparticulate zirconia-modified solid solutions of aluminum-iron oxides for polishing titanium metal. Diagnostics, Resource and Mechanics of materials and structure, 2015, iss. 1, pp. 90–102. DOI: 10.17804/2410-9908. Available at: https://dream-journal.org/DREAM_Issue_1_2015_Koroleva_L._F..pdf
- Koroleva L.F. Modifitsyrovannye oksidy, oksogidroksid, shpineli khroma, dlya abrazivnykh i pigmentnykh materialov [Modified Oxides, Oxyhydroxide, Chromium Spinels for Abrasive and Pigmentary Materials]. Ekaterinburg, UrO RAN Publ., 2002, 217 p. ISBN 5-7691-1236-0. (In Russian).
- Koroleva L.F. Abrasive properties of aluminum iron oxide nanoparticles. Inorganic Materials, 2009, vol. 45 (10), pp. 1158–1165. DOI: 10.1134/S0020168509100148.
- Isasi-Marín J., Pérez-Estébanez M., Díaz-Guerra C., Castillo J.F., Correcher V., Cuervo-Rodríguez M.R. Structural, magnetic and luminescent characteristics of Pr3+-doped ZrO2 powders synthesized by a sol–gel method. Journal of Physics D: Applied Physics, 2009, vol. 42, No. 7. DOI: 10.1088/0022-3727/42/7/075418.
Л. Ф. Королева, Р. А. Саврай, Е. Ю. Просвиряков, В. А. Костарев, С. В. Павлышко, П. В. Костарев
ВЛИЯНИЕ ДОБАВОК АБРАЗИВНОГО МАТЕРИАЛА НА ТРИБОТЕХНИЧЕСКИЕ СВОЙСТВА СМАЗКИ ДЛЯ СИСТЕМЫ «КОЛЕСО–РЕЛЬС»
В работе исследованы полирующая способность трибохимически активного абразивного материала на основе твердого раствора оксидов железа и алюминия, а также твердого раствора оксидов алюминия и железа, модифицированного добавками оксидов циркония и иттрия, и триботехнические свойства смазки с добавками данных абразивных материалов. Установлено, что модифицированные порошки Al2O3·Fe2O3·ZrO2·Y2O3 обладают существенно более высокой полирующей способностью и обеспечивают существенно более низкую шероховатость поверхности, чем немодифицированный порошок Al2O3·Fe2O3. При этом, варьируя содержание модифицирующих оксидов, можно менять трибохимическую активность абразивного порошка и подбирать наилучший состав в зависимости от полируемого материала. Показано, что добавка данных абразивных порошков оказывает существенное влияние на триботехнические свойства смазки для контакта «колесо–рельс». По результатам лабораторных испытаний исследуемых смазочных композиций можно предположить эффективность их использования для контакта «колесо–рельс».
Благодарность: Работа выполнена в рамках государственного задания ИМАШ УрО РАН по темам № АААА-А18-118020790142-9 и № АААА-А18-118020790147-4.
Оптическая профилометрия и триботехнические испытания выполнены в ЦКП «Пластометрия» ИМАШ УрО РАН. Ключевые слова: трибохимически активный абразивный материал, полирующая способность, шероховатость поверхности, смазка для системы «колесо–рельс», нагрузка сваривания, диаметр пятна износа Библиография:
- Применение смазки для системы «колесо–рельс». Решение проблемы износа с использованием отходов производства / Б. Тувшинтур, Д. И. Винокуров, Г. А. Якимова, В. Е. Гозбенко // Системы. Методы. Технологии. – 2015. – № 3 (27). – С. 23–31.
- Artemov A. S. Polishing nanodiamonds // Phys. Solid State. – 2004. – Vol. 46. – P. 687–695. – DOI: 10.1134/1.1711453.
- Jackson M. J., Mills B., Hitchiner M. P. Controlled wear of vitrified abrasive materials for precision grinding applications // Sadhana. – 2003. – Vol. 28, No. 5. – P. 897–914. – DOI: 10.1007/BF02703320 .
- Bakharev V. P. Dispersion of Ceramics and Composites in Diamond Finishing by Free Abra-sive // Russ. Engin. Res. – 2009. – Vol. 29, No. 2. – P. 162–168. – DOI: 10.3103/S1068798X09020129.
- Assessment of surface roughness and reflectance of nonmetallic products upon diamond abrasive finishing / Yu. D. Filatov, V. P. Yashchuk, A. Yu. Filatov, U. Heisel, M. Storchak and G. Monteil // J. Superhard Mater. – 2009. – Vol. 31. – P. 338–346 – DOI: 10.3103/S1063457609050098.
- Storozhenko P. A., Guseinov Sh. L., and Malashin S. I. Nanodispersed powders: synthesis methods and practical applications // Nanotekhnol. Russia. – 2009. – Vol. 4, Nos. 5–6. – P. 262–274. – DOI: 10.1134/S1995078009050024.
- Pokropivnyi V. V., Silenko P. M. Silicon carbide nanotubes and nanotubular fibers: synthe-sis, stability, structure and classification // Theor. Exp. Chem. – 2006. – Vol. 42, No. 1. – P. 3–15. – DOI: 10.1007/s11237-006-0010-y.
- Khanra A. K. Production of boron carbide powder by carbothermal synthesis of gel material // Bull. Mater. Sci. – 2007. – Vol. 30, No. 2. – P. 93–96. – DOI: 10.1007/s12034-007-0016-7.
- Bogdanov S. P. Influence of superstoichiometric boron on the Synthesis of cubic Boron ni-tride // Glass Physics and Chemistry. – 2008. – Vol. 34, No. 3. – P. 336–339. – DOI: 10.1134/S1087659608030164.
- An abrasive-resistant corundum ceramic for drawing microwires / E. V. Degtyareva, I. I. Kabakova, E. B. Skorodumova, V. E. Armyanovskii // Refractories. – 1982. – Vol. 23, Nos. 1–2. – P. 82–87. – DOI: 10.1007/BF01397952.
- Гаршин А. П., Гропянов В. М., Лагунов Ю. В. Абразивные материалы. – Л. : Маши-ностроение, 1983. – 230 с.
- Viktorov V. V., Fotiev A. A., and Badich V. D. Abrasive and Thermal Properties of Al2O3–Cr2O3 Solid Solutions // Inorg. Mater. – 1996. – Vol. 32, No. 1. – P. 55–57.
- Котов Ю. А., Саматов О. М. Характеристики порошков оксида алюминия, получен-ных импульсным нагревом проволоки // Поверхность. – 1994. – № 10–14. – С. 90–94.
- A sol-gel method for synthesizing porous iron-aluminum oxide substances and regulating their physicochemical characteristics / V. M. Belousov, V. M. Chertov, É. V. Rozhkova, V. I. Litvin and V. A. Zazhigalov // Theor. Exp. Chem. – 1997. – Vol. 33, No. 2. – P. 103–105. – DOI: 10.1007/BF02765955.
- Королева Л. Ф. Трибохимическая активность абразивных материалов на основе сме-шанных оксидов в процессе полирования металлов // Физика и химия обработки ма-териалов. – 2006. – № 4. – С. 84–92.
- Semi-abrasive free slurry with acid colloidal silica for copper chemical mechanical planariza-tion / Nan-Hoon Kim, Jond-Heun Lim, Sang-Yong Kim, Eui-Goo Chang // Journal of Mate-rial Science: Materials in Electronics. – 2005. – Vol. 16. – P. 629–632. – DOI: 10.1007/s10854-005-3241-0.
- Марченко Е. А. О природе разрушения поверхности металлов при трении. – М. : Наука, 1979. – 118 с.
- Ребиндер П. А. Значение физико-химических процессов при механическом разруше-нии и обработке твердых тел в технике // Вестник АН СССР. – 1940. – № 8. – С. 5–28.
- Koroleva L. F. Modified Nanoparticle Oxides for Final Polishing // Diagnostics, Resource and Mechanics of materials and structures. – 2016. – Iss. 2. – P. 48–73. – DOI: 10.17804/2410-9908.2016.2.048-073. – URL: http://dream-journal.org/DREAM_Issue_2_2016_Koroleva_L.F._048_073.pdf
- Koroleva L. F. Synthesis and abrasive properties of nanoparticulate modified solid solutions of aluminum and iron oxides // Inorganic Materials. – 2019. – Vol. 55 (6). – P. 556–562. – DOI: 10.1134/S0020168519060074.
- Koroleva L. F. Synthesis and abrasive properties of nanoparticulate MoO2-modified Al2-хFeхO3 and Fe2-yAlyO3 solid solutions // Inorg. Materials. – 2010. – Vol. 46, No. 12. – P. 1330–1336. – DOI: 10.1134/S0020168510120113. – ISSN 0020-1685.
- Koroleva L. F. Final polishing of metals to obtain nanoroughened surface // Nanotechnologies in Russia. – 2012. – Vol. 7, Nos. 1–2. – P. 67–75. – DOI: 10.1134/S1995078012010119.
- Koroleva L. F. Nanoparticulate zirconia-modified solid solutions of aluminum-iron oxides for polishing titanium metal // Diagnostics, Resource and Mechanics of materials and struc-ture. – 2015. – Iss. 1. – P. 90–102. – DOI: 10.17804/2410-9908. – URL: https://dream-journal.org/DREAM_Issue_1_2015_Koroleva_L._F..pdf
- Королева Л. Ф. Модифицированные оксиды, оксогидроксид, шпинели хрома для абразивных и пигментных материалов. – Екатеринбург : УрО РАН, 2002. – 214 с.
- Koroleva L. F. Abrasive properties of aluminum iron oxide nanoparticles // Inorg. Materials. – 2009. – Vol. 45, No. 10. – P. 1158–1165. – DOI: 10.1134/S0020168509100148.
- Structural, magnetic and luminescent characteristics of Pr3+-doped ZrO2 powders synthesized by a sol–gel method / J. Isasi-Marín, M. Pérez-Estébanez, C. Díaz-Guerra, J. F. Castillo, V. Correcher, M. R. Cuervo-Rodríguez // Journal of Physics D: Applied Physics. – 2009. – Vol. 42, No. 7. – DOI: 10.1088/0022-3727/42/7/075418.
Библиографическая ссылка на статью
The Effect of Abrasive Additives on the Tribotechnical Properties of Lubricants for the Wheel–rail System / L. F. Koroleva, R. A. Savrai, E. Yu. Prosviryakov, V. A. Kostarev, S. V. Pavlyshko, P. V. Kostarev // Diagnostics, Resource and Mechanics of materials and structures. -
2023. - Iss. 1. - P. 54-64. - DOI: 10.17804/2410-9908.2023.1.054-064. -
URL: http://dream-journal.org/issues/content/article_390.html (accessed: 10.12.2024).
|