V. V. Chebodaeva, M. B. Sedelnikova, O. V. Bakina, Yu. P. Sharkeev
ELEMENTAL COMPOSITION OF CALCIUM PHOSPHATE COATINGS MODIFIED WITH Fe-Cu NANOPARTICLES
DOI: 10.17804/2410-9908.2021.4.015-022 The object of research is calcium-phosphate coatings doped with Fe-Cu nanoparticles. The elemental composition of the calcium-phosphate (CаP) coatings deposited by the microarc oxidation (MAO) method at a voltage of 250 V is studied. The quantitative content and distribution of Ca, P, O, Ti, Fe, and Cu over the coating surface prove to depend on the introduced additional electrolyte components. After modification with Fe-Cu nanoparticles, the Ca content increases from 4.5 to 6.7 at.%. The amount of P and Ti after the introduction of nanoparticles increases from 11.7 to 22.3 at.% and from 7.9 to 15.8 at.%. Oxygen concentration, on the contrary, decreases from 75.9 to 55.0 at.%.
Acknowledgements: The work was performed within the state assignment to the ISPMS SB RAS, project FWRW-2021-0007. Keywords: calcium-phosphate coatings, hydroxyapatite, Fe-Cu nanocomposite particles, nanoparticles, microarc oxidation Bibliography:
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В. В. Чебодаева, М. Б. Седельникова, О. В. Бакина, Ю. П. Шаркеев
ЭЛЕМЕНТНЫЙ СОСТАВ КАЛЬЦИЙ-ФОСФАТНЫХ ПОКРЫТИЙ МОДИФИЦИ-РОВАННЫХ НАНОЧАСТИЦАМИ Fe-Cu
Объект исследования – кальций-фосфатные покрытия с введенными в их состав наночастицами Fe-Cu. Проведено исследование элементного состава и распределения элементов кальций-фосфатных (КФ) покрытий, нанесенных методом микродугового окисления (МДО). Установлено, что количественное содержание и распределение элементов Ca, P, O, Ti, Fe и Cu в поверхностном слое покрытия существенно зависит от введенных дополнительных компонентов электролита. После модификации наночастицами Fe-Cu содержание Ca увеличивается от 4,5 до 6,7 ат. %, а количество P и Ti увеличивается от 11,7 до 22,3 ат. % и от 7,9 до 15,8 ат. % соответственно. При этом концентрация кислорода уменьшается от 75,9 до 55,0 ат. %. Показано, что такое поведение элементов в покрытии определяется участием ионов металлов Fe3+ и Cu2+ во время осаждения покрытия, способствующих интенсификации процессов МДО.
Благодарности: Работа выполнена в рамках государственного задания ИФПМ СО РАН, проект FWRW-2021-0007. Ключевые слова: кальций-фосфатные покрытия, гидроксиапатит, нанокомпозитные частицы Fe-Cu, наноча-стицы, микродуговое оксидирование Библиография:
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Библиографическая ссылка на статью
Elemental Composition of Calcium Phosphate Coatings Modified with Fe-Cu Nanoparticles / V. V. Chebodaeva, M. B. Sedelnikova, O. V. Bakina, Yu. P. Sharkeev // Diagnostics, Resource and Mechanics of materials and structures. -
2021. - Iss. 4. - P. 15-22. - DOI: 10.17804/2410-9908.2021.4.015-022. -
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