Nanoparticulate Zirconia-Modified Solid Solutions of Aluminum-Iron Oxides for Polishing Titanium Metal

L. F. Koroleva

doi:10.17804/2410-9908.2015.1.090-102

L. F. Koroleva

NANOPARTICULATE ZIRCONIA-MODIFIED SOLID SOLUTIONS OF ALUMINUM-IRON OXIDES FOR POLISHING TITANIUM METAL

DOI: 10.17804/2410-9908.2015.1.090-102

A synthesis mechanism of nanoparticulate zirconia-modified Al_2–xFe_xO₃ solid solutions has been studied with the application of X-ray diffraction, IR spectroscopy, DTA, particle-size analysis and chemical analysis. The solid solutions have been prepared via heat treatment of ammonium hydroxycarbonate complexes. The nanoparticles are shown to consist of crystalline rhombohedral α-Al_2–xFe_xO₃, monoclinic and tetragonal (M-ZrO₂ and T-ZrO₂). The synthesized mixed oxide offers a high polishing ability (3 to 4.5 times as high), as demonstrated in polishing of titanium, and ensures surface roughness values Ra ranging between 0.019 and 0.009 μm.

Keywords: aluminum-iron oxides, zirconia, X-Ray diffraction, polishing, titanium, nano-roughened surface.

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$Fig. 2. XRD patterns of aluminum-iron oxide samples: (a) modified with 0.004-0.008 mol % ZrO2 (the diffraction lines of tetragonal ZrO2 are marked with “o” and the diffraction lines of monoclinic ZrO2 are marked with “x”), the counting being 5 s for each$

Л. Ф. Королева

НАНОДИСПЕРСНЫЕ МОДИФИЦИРОВАННЫЕ ДИОКСИДОМ ЦИРКОНИЯ ТВЕРДЫЕ РАСТВОРЫ ОКСИДОВ АЛЮМИНИЯ И ЖЕЛЕЗА ДЛЯ ПОЛИРОВАНИЯ ТИТАНА

С применением методов рентгеновской дифракции, ИК спектроскопии, анализа размера частиц и химического анализа был выяснен общий механизм формирования наночастиц твердых растворов Al2–xFexO3, модифицированных диоксидом циркония, полученных в результате термообработки комплексов гидроксокарбонатов. Показано, что наночастицы состоят из кристаллического ромбоэдрического α-Al2-xFexO3, моноклинного и тригонального диоксидов циркония (M-ZrO2 и T-ZrO2). Синтезированные сложные оксиды обеспечивают высокую полирующую способность (в 3-4,5 раза выше, чем немодифицированные) в полировании титана. Значение шероховатости поверхности Ra достигается 0,019- 0,009 мкм.

Ключевые слова: оксиды алюминия и железа, оксид циркония, РФА, полирование, титан, наношероховатая поверхность

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Библиографическая ссылка на статью

Koroleva L. F. Nanoparticulate Zirconia-Modified Solid Solutions of Aluminum-Iron Oxides for Polishing Titanium Metal // Diagnostics, Resource and Mechanics of materials and structures. - 2015. - Iss. 1. - P. 90-102. -
DOI: 10.17804/2410-9908.2015.1.090-102. -
URL: http://dream-journal.org/issues/2015-1/2015-1_10.html
(accessed: 21.12.2024).