Investigation of Butadiene-Elastomer-Based High Modulus Materials Reinforced by Basalt, Glass, and Carbon Fabrics

M. M. Kopyrin; A. E. Markov; A. A. Dyakonov; А. G. Tuisov; А. А. Okhlopkova; A. K. Kychkin; N. N. Lazareva

doi:10.17804/2410-9908.2022.3.006-012

M. M. Kopyrin, A. E. Markov, A. A. Dyakonov, А. G. Tuisov, А. А. Okhlopkova, A. K. Kychkin, N. N. Lazareva

INVESTIGATION OF BUTADIENE-ELASTOMER-BASED HIGH MODULUS MATERIALS REINFORCED BY BASALT, GLASS, AND CARBON FABRICS

DOI: 10.17804/2410-9908.2022.3.006-012

A relevant task in improving the properties of elastomers is to increase their strength and stiffness, which affect the reliability and durability of rubber products. The paper presents a technology for manufacturing high-modulus materials based on SKD-V butadiene rubber and reinforcing layers of fabrics from basalt, glass, and carbon fibers. The results of studying elastic strength properties reveal a significant increase in the ultimate strength of reinforced samples in comparison with an unmodified elastomer. The increase in tensile strength varies from 1.7 to 2.8 times. The addition of reinforcing layers reduced the elongation value by 25 to 47 times compared to rubber without reinforcement. High tensile strength and low elongation increase shear resistance. The wear resistance testing of elastomers coated with reinforcing fabrics shows a decrease in abrasion resistance reduced by a factor of 5.8. Abrasion wear and interaction between the reinforcing filler and the polymer are studied by electron microscopy. The study of the microstructure shows a weak contact between the fiber and the elastomeric matrix. Lack of contact during the abrasion process causes destruction of the fibers on the abrasive surface and their further separation. Due to the combination of high tensile strength and low elongation, the reinforced materials obtain high modulus properties combined with lateral mobility.

Acknowledgement: This work was supported by the Ministry of Education and Science of the Russian Federation under state assignments Nos. FSRG-2020-0017 and FWRS-2022-0001. The research used the scientific equipment of the shared research facilities of the Federal Research Center of the Yakut Scientific Center, SB RAS; it was performed as part of the activities under grant No. 13.TsKP.21.0016.

Keywords: elastomer, basalt fiber, carbon fiber, glass fiber, high modulus material, microstructure

References:

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М. М. Копырин, А. Е. Марков, А. А. Дьяконов, А. Г. Туисов, А. А. Охлопкова, А. К. Кычкин, Н. Н. Лазарева

ИССЛЕДОВАНИЕ ВЫСОКОМОДУЛЬНЫХ МАТЕРИАЛОВ НА ОСНОВЕ БУТАДИЕНОВОГО ЭЛАСТОМЕРА, АРМИРОВАННЫХ БАЗАЛЬТО-, СТЕКЛО- И УГЛЕТКАНЬЮ

Одной из актуальных задач в полимерном материаловедении является разработка эластомеров, обладающих повышенной прочностью в сочетании с высоким сопротивлением к сдвиговым деформациям, что позволяет расширить область применения материалов.
В работе приведена технология изготовления высокомодульных материалов на основе эластомера и армирующих слоев из базальто-, стекло- и углетканей. По результатам исследования упруго-прочностных свойств наблюдается существенное увеличение предела прочности армированных образцов по сравнению с исходным эластомером. Повышение прочности варьируется от 1,7 до 2,8 раз. Введение армирующих слоев также приводит к существенному (в 25–47 раз) снижению относительного удлинения образцов по сравнению с исходной резиной. Сочетание высокой прочности с низкой способностью к удлиняющим деформациям придает армированным материалам высокомодульные свойства в комплексе с разносторонней подвижностью.

Благодарность: Работа выполнена при поддержке МОН РФ по Государственному заданию № FSRG-2020-0017 и № FWRS-2022-0001. Исследования выполнены с использованием научного обору-дования ЦКП Федерального исследовательского центра Якутского научного центра СО РАН в рамках реализации мероприятий по гранту № 13.ЦКП.21.0016.

Ключевые слова: эластомер, базальтоволокно, углеволокно, стекловолокно, высокомодульный материал, микроструктура

Библиография:

Hollaway L. C. Advanced polymer composites and polymers in the civil infrastructure. – Elsevier, 2001. – 320 p.
Oladele I. O., Omotosho T. F., Adediran A. A. Polymer-Based Composites: An Indispensable Material for Present and Future Applications // International Journal of Polymer Science. – 2020. – Vol. 2020. – P. 1–12. – DOI: 10.1155/2020/8834518.
Bukhina M. F., Kurlyand S. K. Low-temperature behavior of elastomers. – Leiden : VSP/Brill, 2007. – Vol. 31. – 320 p.
Wang H., Yang L., Rempel G. L. Homogeneous Hydrogenation Art of Nitrile Butadiene Rubber: A Review // Polymer Reviews. – 2013. – Vol. 53, No. 2. – P. 192–239. – DOI: 10.1080/00914039608029377.
Surface treatment of Basalt fiber for use in automotive composites / K. V. Balaji, K. Shirvanimoghaddam, G. S. Rajan, A. V. Ellis, M. Naebe // Materials Today Chemistry. – 2020. – Vol. 17. – P. 1–28. – DOI: 10.1016/j.mtchem.2020.100334.
Preparation, Properties and Mechanisms of Carbon Fiber/Polymer Composites for Thermal Management Applications / Z. Ali, Y. Gao, B. Tang, X. Wu, Y. Wang, M. Li, X. Hou, L. Li, N. Jiang, J. Yu // Polymers. – 2021. – Vol. 13, No. 169. – P. 1–22. – DOI: 10.3390/polym13010169.
Newcomb B. A. Processing, structure, and properties of carbon fibers // Composites Part A: Applied Science and Manufacturing. – 2016. – Vol. 91, No. 1. – P. 262–282. – DOI: 10.1016/j.compositesa.2016.10.018.
Tang X., Yan X. A review on the damping properties of fiber reinforced polymer // Journal of Industrial Textiles. – 2020. – Vol. 49, No. 6. – P. 693–721. – DOI: 10.1177/1528083718795914.
Investigation of basalt fiber composite mechanical properties for applications in transportation / Q. Liu, M. T. Shaw, R. S. Parnas, A. M. McDonnell // Polymer composites. – 2006. – Vol. 27, No. 1. – P. 41–48. – DOI: 10.1002/pc.20162.
Lee C., Liu D. Tensile Strength of Stitching Joint in Woven Glass Fabrics // J. Eng. Mater. Tech. – 1990. – Vol. 112, No. 2. – P. 125–130. – DOI: 10.1115/1.2903298.
Newcomb B. A. Processing, structure, and properties of carbon fibers // Composites Part A: Applied Science and Manufacturing. – 2016. – Vol. 91. – P. 262–282. – DOI: 10.1016/J.COMPOSITESA.2016.10.018.
Temperature–humidity corrosion behavior of basalt epoxy plastics / A. A. Dalinkevich, K. Z. Gumargalieva, S. S. Marakhovskii, A. V. Aseev // Prot. Met. Phys. Chem. Surf. – 2015. – Vol. 51. – P. 1176–1184. – DOI: 10.1134/S2070205115070060.
Liu Y., Kumar S. Recent Progress in Fabrication, Structure, and Properties of Carbon Fibers // Polymer Reviews. – 2012. – Vol. 52, No. 3. – P. 234–258. – DOI: 10.1080/15583724.2012.705410.
Development and application of carbon fiber in batteries / S. Yang, Y. Cheng, X. Xiao, H. Pang // Chemical Engineering Journal. – 2020. – Vol. 384. – P. 123294. – DOI: 10.1016/j.cej.2019.123294.
Schutte C. L. Environmental durability of glass-fiber composites // Materials Science and Engineering: R: Reports. – 1994. – Vol. 13, No. 7. – P. 265–323. – DOI: 10.1016/0927-796x(94)90002-7.
Thermal and crystallization behaviour of epoxidized high cis-polybutadiene rubber / M. L. Dias, F. A. Schoene, C. Ramirez, I. A. Graciano., L. Sirelli, R. P. Gonçalves // Journal of Rubber Research. – 2019. – Vol. 22, No. 4. – P. 195–201. – DOI: 10.1007/s42464-019-00028-5.

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Investigation of Butadiene-Elastomer-Based High Modulus Materials Reinforced by Basalt, Glass, and Carbon Fabrics / M. M. Kopyrin, A. E. Markov, A. A. Dyakonov, А. G. Tuisov, А. А. Okhlopkova, A. K. Kychkin, N. N. Lazareva // Diagnostics, Resource and Mechanics of materials and structures. - 2022. - Iss. 3. - P. 6-12. -
DOI: 10.17804/2410-9908.2022.3.006-012. -
URL: http://dream-journal.org/issues/2022-3/2022-3_366.html
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