Elemental Composition of Calcium Phosphate Coatings Modified with Fe-Cu Nanoparticles

V. V. Chebodaeva; M. B. Sedelnikova; O. V. Bakina; Yu. P. Sharkeev

doi:10.17804/2410-9908.2021.4.015-022

V. V. Chebodaeva, M. B. Sedelnikova, O. V. Bakina, Yu. P. Sharkeev

ELEMENTAL COMPOSITION OF CALCIUM PHOSPHATE COATINGS MODIFIED WITH Fe-Cu NANOPARTICLES

DOI: 10.17804/2410-9908.2021.4.015-022

The object of research is calcium-phosphate coatings doped with Fe-Cu nanoparticles. The elemental composition of the calcium-phosphate (CаP) coatings deposited by the microarc oxidation (MAO) method at a voltage of 250 V is studied. The quantitative content and distribution of Ca, P, O, Ti, Fe, and Cu over the coating surface prove to depend on the introduced additional electrolyte components. After modification with Fe-Cu nanoparticles, the Ca content increases from 4.5 to 6.7 at.%. The amount of P and Ti after the introduction of nanoparticles increases from 11.7 to 22.3 at.% and from 7.9 to 15.8 at.%. Oxygen concentration, on the contrary, decreases from 75.9 to 55.0 at.%.

Acknowledgements: The work was performed within the state assignment to the ISPMS SB RAS, project FWRW-2021-0007.

Keywords: calcium-phosphate coatings, hydroxyapatite, Fe-Cu nanocomposite particles, nanoparticles, microarc oxidation

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В. В. Чебодаева, М. Б. Седельникова, О. В. Бакина, Ю. П. Шаркеев

ЭЛЕМЕНТНЫЙ СОСТАВ КАЛЬЦИЙ-ФОСФАТНЫХ ПОКРЫТИЙ МОДИФИЦИ-РОВАННЫХ НАНОЧАСТИЦАМИ Fe-Cu

Объект исследования – кальций-фосфатные покрытия с введенными в их состав наночастицами Fe-Cu. Проведено исследование элементного состава и распределения элементов кальций-фосфатных (КФ) покрытий, нанесенных методом микродугового окисления (МДО). Установлено, что количественное содержание и распределение элементов Ca, P, O, Ti, Fe и Cu в поверхностном слое покрытия существенно зависит от введенных дополнительных компонентов электролита. После модификации наночастицами Fe-Cu содержание Ca увеличивается от 4,5 до 6,7 ат. %, а количество P и Ti увеличивается от 11,7 до 22,3 ат. % и от 7,9 до 15,8 ат. % соответственно. При этом концентрация кислорода уменьшается от 75,9 до 55,0 ат. %. Показано, что такое поведение элементов в покрытии определяется участием ионов металлов Fe3+ и Cu2+ во время осаждения покрытия, способствующих интенсификации процессов МДО.

Благодарности: Работа выполнена в рамках государственного задания ИФПМ СО РАН, проект FWRW-2021-0007.

Ключевые слова: кальций-фосфатные покрытия, гидроксиапатит, нанокомпозитные частицы Fe-Cu, наноча-стицы, микродуговое оксидирование

Библиография:

Биокомпозиты на основе кальцийфосфатных покрытий, наноструктурных и ультрамелкозернистых биоинертных металлов, их биосовместимость и биодеградация / Ю. П. Шаркеев, С. Г. Псахье, Е. В. Легостаева, А. Г. Князева, А. Ю. Смолин, А. Ю. Ерошенко и др. – Томск : Издательский Дом Томского государственного университета, 2014. – 596 с.
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Composite polymer-bioceramic scaffolds with drug delivery capability for bone tissue engineering / V. Mouriño, J. P. Cattalini, J. A. Roether, P. Dubey, I. Roy, A. R. Boccaccini // Expert Opinion on Drug Delivery. – 2013. – Vol. 10 (10). – P. 1353–1365. – DOI: 10.1517/17425247.2013.808183.
Structural, morphological and adhesive properties of calcium phosphate coatings formed on magnesium alloy by micro-arc oxidation method in electrolyte containing dispersed particles / M. B. Sedelnikova, A. V. Ugodchikova, P. V. Uvarkin, V. V. Chebodaeva, T. V. Tolkacheva, D. Schmidt, Yu. P. Sharkeev // Russian Physics Journal. – 2021. – DOI: 10.1007/s11182-021-02398-z.
Surface modification of Mg0.8Ca alloy via wollastonite micro-arc coatings: Significant improvement in corrosion resistance / M. B. Sedelnikova, A. V. Ugodchikova, T. V. Tolkacheva, V. V. Chebodaeva, I. A. Cluklhov, M. A. Khimich, O. V. Bakina, M. I. Lerner, V. S. Egorkin, J. Schmidt, Y. P. Sharkeev // Metals. – 2021. – Vol. 11 (5). – 754. – DOI: 10.3390/met11050754.
Influence of electrolyte composition on microstructure, adhesion and bioactivity of micro-arc oxidation coatings produced on biomedical Ti6Al7Nb alloy / J. Karbowniczek, F. Muhaffel, G. Cempura, H. Cimenoglu, A. Czyrska-Filemonowicz // Surface and Coatings Technology. – 2017. – Vol. 321. – P. 97–107. – DOI: 10.1016/j.surfcoat.2017.04.031.
Introduction to plasma electrolytic oxidation—an overview of the process and applications / F. Simchen, M. Sieber, A. Kopp, T. Lampke // Coatings. – 2020. – Vol. 628 (10). – DOI: 10.3390/coatings10070628.
Dorozhkin S. V. Calcium orthophosphate deposits: Preparation, properties and biomedical applications // Materials Science and Engineering C. – 2015. – Vol. 55. – P. 272–326. – DOI: 10.1016/j.msec.2015.05.033.
Influence of current density and electrolyte concentration on DC PEO titania coatings / R. H. U. Khan, A. L. Yerokhin, X. Li, H. Dong, A. Matthews // Surface Engineering. – 2014. – Vol. 30 (2). – P. 102–108. – DOI: 10.1179/1743294413Y.0000000225.
Effect of Boehmite Nanoparticles on the Structural, Corrosion, and Diffusion Properties of Microarc Biocoatings / V. V. Chebodaeva, N. N. Nazarenko, M. B. Sedelnikova, S. V. Gnedenkov, V. S. Egorkin, S. L. Sinebryukhov, and Yu. P. Sharkeev // Inorganic Materials: Applied Research. – 2021. – Vol. 12, No. 3. – P. 691–699. – DOI: 10.1134/S2075113321030072.
Influence of Metal Based Nanoparticles on Properties of Micro-arc Calcium Phosphate Coatings / V. Chebodaeva, M. Sedelnikova, V. Bazhanova, M. Lerner, A. Pervikov, Yu. Sharkeev // AIP Conference proceedings – 2019. – Vol. 2167. – P. 020049-1–020049-4. – DOI: 10.1063/1.5131916.
Fabrication of Fe-Cu composites from electroexplosive bimetallic nanoparticles by spark plasma sintering / A. S. Lozhkomoev, A. V. Pervikov, A. V. Chumaevsky, E. S. Dvilis, V. D. Paygin, O. L. Khasanov, M. I. Lerner // Vacuum. – 2019. – Vol. 170. – 108980. – DOI: 10.1016/j.vacuum.2019.108980.
Control of smooth muscle cell proliferation by ferrous iron / P. P. Mueller, T. May, A. Perz, H. Hauser, M. Peuster // Biomaterials. – 2006. – Vol. 27. – P. 2193–2200. – DOI: 10.1016/j.biomaterials.2005.10.042.
Fabrication of Fe-Cu composites from electroexplosive bimetallic nanoparticles by spark plasma sintering / A. S. Lozhkomoev, A. V. Pervikov, A. V. Chumaevsky, E. S. Dvilis, V. D. Paygin, O. L. Khasanov, M. I. Lerner // Vacuum. – 2019. – Vol. 170. – P. 108980. – DOI: 10.1016/j.vacuum.2019.108980.

Библиографическая ссылка на статью

Elemental Composition of Calcium Phosphate Coatings Modified with Fe-Cu Nanoparticles / V. V. Chebodaeva, M. B. Sedelnikova, O. V. Bakina, Yu. P. Sharkeev // Diagnostics, Resource and Mechanics of materials and structures. - 2021. - Iss. 4. - P. 15-22. -
DOI: 10.17804/2410-9908.2021.4.015-022. -
URL: http://dream-journal.org/issues/2021-4/2021-4_333.html
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